According to his wife Candie, one of Guy's most important roles during the Civil Rights Movement—more so than introducing "We Shall Overcome" as a Freedom Song—was his desire to record and archive the evolution of the movement through song. Both Guy and Candie believe that the political usage of religious and folk music could shape movements and influence people to take action in social change, and Guy's initiative to record and preserve the already established Freedom Songs within the movement are used to inspire and to educate future leaders and activists. Movement leader Rev. C. T. Vivian, a lieutenant of Martin Luther King reminisced:
I don’t think we had ever thought of spirituals as movement material. When the movement came up, we couldn’t apply them. The concept has to be there. It wasn’t just to have the music but to take the music out of our past and apply it to the new situation, to change it so it really fit.... The first time I remember any change in our songs was when Guy came down from Highlander. Here he was with this guitar and tall thin frame, leaning forward and patting that foot. I remember James Bevel and I looked across at each other and smiled. Guy had taken this song, "Follow the Drinking Gourd" – I didn't know the song, but he gave some background on it and boom – that began to make sense. And, little by little, spiritual after spiritual began to appear with new words and changes: “"Keep Your Eyes on the Prize", "Hold On" or "I’m Going to Sit at the Welcome Table". Once we had seen it done, we could begin to do it.
At Highlander's April workshop, Carawan had met Candie Anderson, an exchange student at Fisk University in Nashville, from Pomona College in California, who was one of the first white students involved in the sit-in movement. They were married in March 1961.
Guy and Candie Carawan, compilers, We Shall Overcome! (New York: Oak Publications, 1963).
Guy and Candie Carawan, recorders and editors, photographed by Robert Yellin, Ain't You Got a Right to the Tree of Life? The People of Johns Island, South Carolina – their faces, their words and their songs (1966; University of Georgia Press, 1989). ISBN 0-8203-1132-4
Guy and Candie Carawan, compilers, Freedom is a Constant Struggle (New York: Oak Publications, 1968).
Guy and Candie Carawan, collectors and recorders, Voices from the Mountains: Life and Struggle in the Appalachian South (1975; University of Georgia Press, 1996). ISBN 0-8203-1882-5
Guy and Candie Carawan, editors and compilers, Sing for Freedom: The Story of the Civil Rights Movement through Its Songs (Bethlehem, PA: Sing Out Corp., 1990, 1992; NewSouth Books, 2008). ISBN 978-1-58838-193-4 (incorporates We Shall Overcome! and Freedom is a Constant Struggle above)
May Justus, The Carawan Recordings, summer 1953, Horton living room in Monteagle, TN; 1961 at May's Summerfield home. Recorded by Guy Carawan; published in 2011 by Tennessee Folklore Society and Jubilee Community Arts 
Nashville Sit-In Story. Folkways Records, FH#5590, 1960. Recorded by Guy Carawan, assisted by Mel Kaiser at Cue Studio.
Hamper McBee, Cumberland Moonshiner. Prestige Records, 1965. Recorded by Guy Carawan in Knoxville, TN, April 6, 1962.
Freedom in the Air: Albany Georgia, 1961–62. SNCC #101. Produced by Vanguard Records for the Student Nonviolent Coordinating Committee. Recorded by Guy Carawan. Produced by Guy Carawan & Alan Lomax.
We Shall Overcome, Songs of Freedom Riders and the Sit-Ins. Folkways Records, FH#5591, 1963. Includes Nashville Quartet and Montgomery Trio. Recorded in New York City.
Birmingham, Alabama, 1963. Mass Meeting. Folkways Records, FD#5487, 1980. Includes Martin Luther King, Jr., Ralph Abernathy, Birmingham Movement Choir. Recorded by Guy Carawan in Birmingham, AL.
Sea Island Folk Festival: Moving Star Hall Singers. Folkways Records, FS#3841, 1966. Includes Alan Lomax speaking at festival. Recorded and produced by Guy & Candie Carawan.
Been in the Storm So Long: Spirituals, Shouts, Folk Tales and Children’s Songs of Johns Island, South Carolina. Folkways Records, FS#3842, 1967. Recorded and produced by Guy & Candie Carawan.
Earl Gilmore: From the Depths of My Soul.June Appal Recordings, JA0022, 1967. Produced and edited by Guy Carawan for June Appal Recordings. Includes Rupert Oysler on harmonica. Recorded by Jack Wright and Jeff Kiser.
Come All You Coal Miners. Rounder Records, #4005, 1974. Includes Nimrod Workman, Sarah Gunning, George Tucker, Hazel Dickens. Recorded by Roger and Lucy Phenix at Appalachian Music Workshop at Highlander Center, October 1972. Produced by Guy Carawan.
George Tucker, Kentucky Coal Miner. Rounder Records, #0064, 1975. Collected and recorded by Guy Carawan in Beaver, KY.
China: Music from the Peoples’ Republic. Rounder Records, #4008, CD, 1976. Recorded in China by Guy and Candie Carawan.
Sing for Freedom, Southwide Workshop. Folkways Records, FD#5488, 1980. Produced by Guy & Candie Carawan, Highlander Center. Recorded at the Gammon Theological Seminary in Atlanta, GA, at a workshop with Freedom Singers, Birmingham Movement Choir, Georgia Sea Island Singers, Doc Reese, Phil Ochs, and Len Chandler.
They'll Never Keep Us Down: Women’s coal mining songs. Rounder Records, #4012, 1983. Includes Hazel Dickens, Sarah Gunning, Florence Reece, Phyllis Boyens, Reel World String Band. Dedicated to Sarah Gunning who died November 14, 1983. Produced by Guy & Candie Carawan for Rounder.
Sing for Freedom. Smithsonian Folkways, SF#40032, CD, 1990. A compilation of material from the six LPs. Selected by Guy & Candie Carawan.
Been in the Storm So Long. Smithsonian Folkways, SF#40031, CD, 1990. A compilation of material from the two LPs. Selected by Guy & Candie Carawan.
Coal Mining Women. Rounder Records, #4025, CD, 1997. Selections from two previous coal LPs. Conceived and selected by Guy and Candie Carawan.
The Telling Takes Me Home, Heatcar Productions <http://www.heatcar.com/>, 2005; produced, directed and edited by Heather Carawan, 29 min. Music and memory tell the story of Guy and Candie Carawan, activists and folk singers who have carried their work from the deep south of the Civil Rights Movement into today's daunting struggle for peace. Interweaving past and present, the filmmaker integrates her own reflections on growing up in a rich musical and political landscape with her parents' views on race relations, community organizing, and the sustaining power of song.