The internal combustion engine is an engine in which the combustion of a fuel (normally a fossil fuel) occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal combustion engine (ICE) the expansion of the high-temperature and high-pressure gases produced by combustion apply direct force to some component of the engine. The force is applied typically to pistons, turbine blades, or a nozzle. This force moves the component over a distance, transforming chemical energy into useful mechanical energy. The first commercially successful internal combustion engine was created by Étienne Lenoir.
The term internal combustion engine usually refers to an engine in which combustion is intermittent, such as the more familiar four-stroke and two-stroke piston engines, along with variants, such as the six-stroke piston engine and the Wankel rotary engine. A second class of internal combustion engines use continuous combustion: gas turbines, jet engines and most rocket engines, each of which are internal combustion engines on the same principle as previously described.
The ICE is quite different from external combustion engines, such as steam or Stirling engines, in which the energy is delivered to a working fluid not consisting of, mixed with, or contaminated by combustion products. Working fluids can be air, hot water, pressurized water or even liquid sodium, heated in some kind of boiler. ICEs are usually powered by energy-dense fuels such as gasoline or diesel, liquids derived from fossil fuels. While there are many stationary applications, most ICEs are used in mobile applications and are the dominant power supply for cars, aircraft, and boats.
At one time, the word, "Engine" (from Latin, via Old French, ingenium, "ability") meant any piece of machinery—a sense that persists in expressions such as siege engine. A "motor" (from Latin motor, "mover") is any machine that produces mechanical power. Traditionally, electric motors are not referred to as "Engines"; however, combustion engines are often referred to as "motors." (An electric engine refers to a locomotive operated by electricity.)
Internal combustion engines are most commonly used for mobile propulsion in vehicles and portable machinery. In mobile equipment, internal combustion is advantageous since it can provide high power-to-weight ratios together with excellent fuel energy density. Generally using fossil fuel (mainly petroleum), these engines have appeared in transport in almost all vehicles (automobiles, trucks, motorcycles, boats, and in a wide variety of aircraft and locomotives).
Where very high power-to-weight ratios are required, internal combustion engines appear in the form of gas turbines. These applications include jet aircraft, helicopters, large ships and electric generators.
Engines can be classified in many different ways: By the engine cycle used, the layout of the engine, source of energy, the use of the engine, or by the cooling system employed.
Internal combustion engines can be classified by their configuration.
Common layouts of engines are:
As their name implies, four-stroke internal combustion engines have four basic steps that repeat with every two revolutions of the engine:
(1) Intake/suction stroke (2) Compression stroke (3) Power/expansion stroke and (4) Exhaust stroke
1. Intake stroke: The first stroke of the internal combustion engine is also known as the suction stroke because the piston moves to the maximum volume position (downward direction in the cylinder). The inlet valve opens as a result of the cam lobe pressing down on the valve stem, and the vaporized fuel mixture enters the combustion chamber. The inlet valve closes at the end of this stroke.
2. Compression stroke: In this stroke, both valves are closed and the piston starts its movement to the minimum volume position (upward direction in the cylinder) and compresses the fuel mixture. During the compression process, pressure, temperature and the density of the fuel mixture increases.
3. A Power stroke: When the piston reaches a point just before top dead center, the spark plug ignites the fuel mixture. The point at which the fuel ignites varies by engine; typically it is about 10 degrees before top dead center. This expansion of gases caused by ignition of the fuel produces the power that is transmitted to the crank shaft mechanism.
4. Exhaust stroke: In the end of the power stroke, the exhaust valve opens. During this stroke, the piston starts its movement in the maximum volume position. The open exhaust valve allows the exhaust gases to escape the cylinder. At the end of this stroke, the exhaust valve closes, the inlet valve opens, and the sequence repeats in the next cycle. Four-stroke engines require two revolutions.
Many engines overlap these steps in time; turbine engines do all steps simultaneously at different parts of the engines.
All internal combustion engines depend on combustion of a chemical fuel, typically with oxygen from the air (though it is possible to inject nitrous oxide to do more of the same thing and gain a power boost). The combustion process typically results in the production of a great quantity of heat, as well as the production of steam and carbon dioxide and other chemicals at very high temperature; the temperature reached is determined by the chemical make up of the fuel and oxidisers (see stoichiometry), as well as by the compression and other factors.
The most common modern fuels are made up of hydrocarbons and are derived mostly from fossil fuels (petroleum). Fossil fuels include diesel fuel, gasoline and petroleum gas, and the rarer use of propane. Except for the fuel delivery components, most internal combustion engines that are designed for gasoline use can run on natural gas or liquefied petroleum gases without major modifications. Large diesels can run with air mixed with gases and a pilot diesel fuel ignition injection. Liquid and gaseous biofuels, such as ethanol and biodiesel (a form of diesel fuel that is produced from crops that yield triglycerides such as soybean oil), can also be used. Engines with appropriate modifications can also run on hydrogen gas, wood gas, or charcoal gas, as well as from so-called producer gas made from other convenient biomass. Recently, experiments have been made with using powdered solid fuels, such as the magnesium injection cycle.
Internal combustion engines require ignition of the mixture, either by spark ignition (SI) or compression ignition (CI). Before the invention of reliable electrical methods, hot tube and flame methods were used. Experimental engines with laser ignition have been built.
Gasoline engine ignition systems generally rely on a combination of a lead–acid battery and an induction coil to provide a high-voltage electric spark to ignite the air-fuel mix in the engine's cylinders. This battery is recharged during operation using an electricity-generating device such as an alternator or generator driven by the engine. Gasoline engines take in a mixture of air and gasoline and compress it to not more than 12.8 bar (1.28 MPa), then use a spark plug to ignite the mixture when it is compressed by the piston head in each cylinder.
While gasoline internal combustion engines are much easier to start in cold weather than diesel engines, they can still have cold weather starting problems under extreme conditions. For years the solution was to park the car in heated areas. In some parts of the world the oil was actually drained and heated over night and returned to the engine for cold starts. In the early 1950s the gasoline Gasifier unit was developed, where part on cold weather starts raw gasoline was diverted to the unit where part of the gas was burned causing the other part to become a hot vapor sent directly to the intake valve manifold. This unit was quite popular till electric engine block heaters became standard on gasoline engines sold in cold climates. 
Diesel engines and HCCI (Homogeneous charge compression ignition) engines, rely solely on heat and pressure created by the engine in its compression process for ignition. The compression level that occurs is usually twice or more than a gasoline engine. Diesel engines take in air only, and shortly before peak compression, spray a small quantity of diesel fuel into the cylinder via a fuel injector that allows the fuel to instantly ignite. HCCI type engines take in both air and fuel, but continue to rely on an unaided auto-combustion process, due to higher pressures and heat. This is also why diesel and HCCI engines are more susceptible to cold-starting issues, although they run just as well in cold weather once started. Light duty diesel engines with indirect injection in automobiles and light trucks employ glowplugs that pre-heat the combustion chamber just before starting to reduce no-start conditions in cold weather. Most diesels also have a battery and charging system; nevertheless, this system is secondary and is added by manufacturers as a luxury for the ease of starting, turning fuel on and off (which can also be done via a switch or mechanical apparatus), and for running auxiliary electrical components and accessories. Most new engines rely on electrical and electronic engine control units (ECU) that also adjust the combustion process to increase efficiency and reduce emissions.
Engines based on the two-stroke cycle use two strokes (one up, one down) for every power stroke. Since there are no dedicated intake or exhaust strokes, alternative methods must be used to scavenge the cylinders. The most common method in spark-ignition two-strokes is to use the downward motion of the piston to pressurize fresh charge in the crankcase, which is then blown through the cylinder through ports in the cylinder walls.
Spark-ignition two-strokes are small and light for their power output and mechanically very simple; however, they are also generally less efficient and more polluting than their four-stroke counterparts. In terms of power per cm³, a two-stroke engine produces comparable power to an equivalent four-stroke engine. The advantage of having one power stroke for every 360° of crankshaft rotation (compared to 720° in a 4-stroke motor) is balanced by the less complete intake and exhaust and the shorter effective compression and power strokes. It may be possible for a two-stroke to produce more power than an equivalent four-stroke, over a narrow range of engine speeds, at the expense of less power at other speeds.
Small displacement, crankcase-scavenged two-stroke engines have been less fuel-efficient than other types of engines when the fuel is mixed with the air prior to scavenging allowing some of it to escape out of the exhaust port. Modern designs (Sarich and Paggio) use air-assisted fuel injection, which avoids this loss and provides more efficiency than comparably sized four-stroke engines. Fuel injection is essential for a modern two-stroke engine for it to meet stringent emission standards. The problem of total loss oil consumption, however, remains a cause of high hydrocarbon emissions. The low-pressure direct gasoline injection developed by R Sarich was tested by Ford in an automobile size 2-stroke engine, and in 2012, Orbital won a contract by the Australia government for a two-stroke, direct injection engine for airborne drones.
Research continues into improving many aspects of two-stroke motors including direct fuel injection, amongst other things. The initial results have produced motors that are much cleaner burning than their traditional counterparts. Two-stroke engines are widely used in snowmobiles, lawnmowers, string trimmers, chain saws, jet skis, mopeds, outboard motors, and many motorcycles. Two-stroke engines have the advantage of an increased specific power ratio (i.e. power to volume ratio), typically around 1.5 times that of a typical four-stroke engine.
The largest internal combustion engines in the world are two-stroke diesels, used in some locomotives and large ships. They use forced induction (similar to super-charging, or turbocharging) to scavenge the cylinders; an example of this type of motor is the Wärtsilä-Sulzer turbocharged two-stroke diesel as used in large container ships. It is the most efficient and powerful internal combustion engine in the world with over 50% thermal efficiency. For comparison, the most efficient small four-stroke motors are around 43% thermal efficiency (SAE 900648); size is an advantage for efficiency due to the increase in the ratio of volume to surface area.
Common cylinder configurations include the straight or inline configuration, the more compact V configuration, and the wider but smoother flat or boxer configuration. Aircraft engines can also adopt a radial configuration, which allows more effective cooling. More unusual configurations such as the H, U, X, and W have also been used.
Multiple crankshaft configurations do not necessarily need a cylinder head at all because they can instead have a piston at each end of the cylinder called an opposed piston design. Because here gas in- and outlets are positioned at opposed ends of the cylinder, one can achieve uniflow scavenging, which, as in the four-stroke engine, is efficient over a wide range of engine speeds. Also the thermal efficiency is improved because of lack of cylinder heads. This design was used in the Junkers Jumo 205 diesel aircraft engine, using two crankshafts at either end of a single bank of cylinders, and most remarkably in the Napier Deltic diesel engines. These used three crankshafts to serve three banks of double-ended cylinders arranged in an equilateral triangle with the crankshafts at the corners. It was also used in single-bank locomotive engines, and is still used for marine propulsion engines and marine auxiliary generators.
The Wankel engine (rotary engine) does not have piston strokes. It operates with the same separation of phases as the four-stroke engine with the phases taking place in separate locations in the engine. In thermodynamic terms it follows the Otto engine cycle, so may be thought of as a "four-phase" engine. While it is true that three power strokes typically occur per rotor revolution due to the 3:1 revolution ratio of the rotor to the eccentric shaft, only one power stroke per shaft revolution actually occurs; this engine provides three power 'strokes' per revolution per rotor giving it a greater power-to-weight ratio than piston engines. This type of engine was most notably used in the Mazda RX-8, the earlier RX-7, and other models.
A gas turbine is a rotary machine similar in principle to a steam turbine and it consists of three main components: a compressor, a combustion chamber, and a turbine. The air, after being compressed in the compressor, is heated by burning fuel in it. About ⅔ of the heated air, combined with the products of combustion, expands in a turbine, producing work output that drives the compressor. The rest (about ⅓) is available as useful work output.
The jet engine takes a large volume of hot gas from a combustion process (typically a gas turbine, but rocket forms of jet propulsion often use solid or liquid propellants, and ramjet forms also lack the gas turbine) and feed it through a nozzle that accelerates the jet to high speed. As the jet accelerates through the nozzle, this creates thrust and in turn does useful work.
This system manages to pack one power stroke into every two strokes of the piston (up-down). This is achieved by exhausting and recharging the cylinder simultaneously.
The steps involved here are:
Two Stroke Spark Ignition (SI) engine:
In a two-stroke SI engine a cycle is completed in two strokes of a piston or one complete revolution (360°) of a crankshaft. In this engine the intake and exhaust strokes are eliminated and ports are used instead of valves. In this cycle, the gasoline is mixed with lubricant oil, resulting in a simpler, but more environmentally damaging system, as the excess oils do not burn and are left as a residue. As the piston proceeds downward another port is opened, the fuel/air intake port. Air/fuel/oil mixtures come from the carburetor, where it was mixed, to rest in an adjacent fuel chamber. When the piston moves further down and the cylinder doesn't have anymore gases, fuel mixture starts to flow to the combustion chamber and the second process of fuel compression starts. The design carefully considers the point that the fuel-air mixture should not mix with the exhaust, therefore the processes of fuel injection and exhausting are synchronized to avoid that concern. It should be noted that the piston has three functions in its operation:
The major components of a two-stroke spark ignition engine are the:
Operation: When the piston moves from bottom dead center (BDC) to top dead center (TDC) the fresh air and fuel mixture enters the crank chamber through the intake port. The mixture enters due to the pressure difference between the crank chamber and the outer atmosphere while simultaneously the fuel-air mixture above the piston is compressed.
Ignition: With the help of a spark plug, ignition takes place at the top of the stroke. Due to the expansion of the gases the piston moves downwards covering the intake port and compressing the fuel-air mixture inside the crank chamber. When the piston is at bottom dead center, the burnt gases escape from the exhaust port.
At the time the transfer port is uncovered the compressed charge from the crank chamber enters into the combustion chamber through the transfer port. The fresh charge is deflected upwards by a hump provided on the top of the piston and removes the exhaust gases from the combustion chamber. Again the piston moves from bottom dead center to top dead center and the fuel-air mixture is compressed when the both the exhaust port and transfer ports are covered. The cycle is repeated.
Advantages: • It has no valves or camshaft mechanism, hence simplifying its mechanism and construction • For one complete revolution of the crankshaft, the engine executes one cycle—the 4-stroke executes one cycle per two crankshafts revolutions. • Less weight and easier to manufacture. • High power-to-weight ratio
Disadvantages: • The lack of lubrication system that protects the engine parts from wear. Accordingly, the 2-stroke engines have a shorter life. • 2-stroke engines do not consume fuel efficiently. • 2-stroke engines produce lots of pollution. • Sometimes part of the fuel leaks to the exhaust with the exhaust gases. In conclusion, based on the above advantages and disadvantages, two-stroke engines are supposed to operate in vehicles where the weight of the engine must be small, and it is not used continuously for long periods.
Engines based on the four-stroke ("Otto cycle") have one power stroke for every four strokes (up-down-up-down) and employ spark plug ignition. Combustion occurs rapidly, and during combustion the volume varies little ("constant volume"). They are used in cars, larger boats, some motorcycles, and many light aircraft. They are generally quieter, more efficient, and larger than their two-stroke counterparts.
The steps involved here are:
Split-cycle engines separate the four strokes of intake, compression, combustion and exhaust into two separate but paired cylinders. The first cylinder is used for intake and compression. The compressed air is then transferred through a crossover passage from the compression cylinder into the second cylinder, where combustion and exhaust occur. A split-cycle engine is really an air compressor on one side with a combustion chamber on the other.
Previous split-cycle engines have had two major problems - poor breathing (volumetric efficiency) and low thermal efficiency. However, new designs are being introduced that seek to address these problems.
The Scuderi Engine addresses the breathing problem by reducing the clearance between the piston and the cylinder head through various turbo charging techniques. The Scuderi design requires the use of outwardly opening valves that enable the piston to move very close to the cylinder head without the interference of the valves. Scuderi addresses the low thermal efficiency via firing ATDC.
Firing ATDC can be accomplished by using high-pressure air in the transfer passage to create sonic flow and high turbulence in the power cylinder.
Most truck and automotive diesel engines use a cycle reminiscent of a four-stroke cycle, but with a compression heating ignition system, rather than needing a separate ignition system. This variation is called the diesel cycle. In the diesel cycle, diesel fuel is injected directly into the cylinder so that combustion occurs at constant pressure, as the piston moves.
Otto cycle: Otto cycle is the typical cycle for most of the cars internal combustion engines, that work using gasoline as a fuel. Otto cycle is exactly the same one that was described for the four-stroke engine. It consists of the same four major steps: Intake, compression, ignition and exhaust.
PV diagram for Otto cycle On the PV-diagram, 1-2: Intake: suction stroke 2-3: Isentropic Compression stroke 3-4: Heat addition stroke 4-5: Exhaust stroke (Isentropic expansion) 5-2: Heat rejection The distance between points 1-2 is the stroke of the engine. By dividing V2/V1, we get: r
where r is called the compression ratio of the engine.
The six-stroke engine was invented in 1883. Four kinds of six-stroke use a regular piston in a regular cylinder (Griffin six-stroke, Bajulaz six-stroke, Velozeta six-stroke and Crower six stroke), firing every three crankshaft revolutions. The systems capture the wasted heat of the four-stroke Otto cycle with an injection of air or water.
A gas turbine is a rotary machine somewhat similar in principle to a steam turbine and it consists of three main components: a compressor, a combustion chamber, and a turbine. The air after being compressed in the compressor is heated by burning fuel in it, this heats and expands the air, and this extra energy is tapped by the turbine, which in turn powers the compressor closing the cycle and powering the shaft.
Gas turbine cycle engines employ a continuous combustion system where compression, combustion, and expansion occur simultaneously at different places in the engine—giving continuous power. Notably, the combustion takes place at constant pressure, rather than with the Otto cycle, constant volume.
The very first internal combustion engines did not compress the mixture. The first part of the piston downstroke drew in a fuel-air mixture, then the inlet valve closed and, in the remainder of the down-stroke, the fuel-air mixture fired. The exhaust valve opened for the piston upstroke. These attempts at imitating the principle of a steam engine were very inefficient.
Engines are often classified by the fuel (or propellant) they used.
Presently, fuels used include:
Even fluidized metal powders and explosives have seen some use. Engines that use gases for fuel are called gas engines and those that use liquid hydrocarbons are called oil engines; however, gasoline engines are also often colloquially referred to as, "gas engines" ("petrol engines" in the UK).
The main limitations on fuels are that it must be easily transportable through the fuel system to the combustion chamber, and that the fuel releases sufficient energy in the form of heat upon combustion to make practical use of the engine.
Diesel engines are generally heavier, noisier, and more powerful at lower speeds than gasoline engines. They are also more fuel-efficient in most circumstances and are used in heavy road vehicles, some automobiles (increasingly so for their increased fuel efficiency over gasoline engines), ships, railway locomotives, and light aircraft. Gasoline engines are used in most other road vehicles including most cars, motorcycles, and mopeds. Note that in Europe, sophisticated diesel-engined cars have taken over about 40% of the market since the 1990s. There are also engines that run on hydrogen, methanol, ethanol, liquefied petroleum gas (LPG), biodiesel, paraffin and tractor vaporizing oil (TVO).
Hydrogen could eventually replace conventional fossil fuels in traditional internal combustion engines. Alternatively fuel cell technology may come to deliver its promise and the use of the internal combustion engines could even be phased out.
Although there are multiple ways of producing free hydrogen, those methods require converting combustible molecules into hydrogen or consuming electric energy. Unless that electricity is produced from a renewable source—and is not required for other purposes— hydrogen does not solve any energy crisis. In many situations the disadvantage of hydrogen, relative to carbon fuels, is its storage. Liquid hydrogen has extremely low density (14 times lower than water) and requires extensive insulation—whilst gaseous hydrogen requires heavy tankage. Even when liquefied, hydrogen has a higher specific energy but the volumetric energetic storage is still roughly five times lower than gasoline. However, the energy density of hydrogen is considerably higher than that of electric batteries, making it a serious contender as an energy carrier to replace fossil fuels. The 'Hydrogen on Demand' process (see direct borohydride fuel cell) creates hydrogen as needed, but has other issues, such as the high price of the sodium borohydride that is the raw material.
|This section does not cite any references or sources. (July 2010)|
Since air is plentiful at the surface of the earth, the oxidizer is typically atmospheric oxygen, which has the advantage of not being stored within the vehicle. This increases the power-to-weight and power-to-volume ratios. Other materials are used for special purposes, often to increase power output or to allow operation under water or in space.
Two most common forms of engine cooling are air-cooled and water cooled — most modern engines are water cooled. Some engines (air or water cooled) also have an oil cooler. Cooling is required to remove excessive heat — over heating can cause engine failure, usually from wear, cracking or warping.
An internal combustion engine is not usually self-starting so an auxiliary machine is required to start it. Many different systems have been used in the past but modern engines are usually started by an electric motor in the small and medium sizes or by compressed air in the large sizes.
Engine types vary greatly in a number of different ways:
Once ignited and burnt, the combustion products—hot gases—have more available thermal energy than the original compressed fuel-air mixture (which had higher chemical energy). The available energy is manifested as high temperature and pressure that can be translated into work by the engine. In a reciprocating engine, the high-pressure gases inside the cylinders drive the engine's pistons.
Once the available energy has been removed, the remaining hot gases are vented (often by opening a valve or exposing the exhaust outlet) and this allows the piston to return to its previous position (top dead center, or TDC). The piston can then proceed to the next phase of its cycle, which varies between engines. Any heat that is not translated into work is normally considered a waste product and is removed from the engine either by an air or liquid cooling system.
Internal combustion engines are primarily heat engines, and as such their theoretical efficiency can be calculated by idealized thermodynamic cycles. The efficiency of a theoretical cycle cannot exceed that of the Carnot cycle, whose efficiency is determined by the difference between the lower and upper operating temperatures of the engine. The upper operating temperature of a terrestrial engine is limited by the thermal stability of the materials used to construct it. All metals and alloys eventually melt or decompose, and there is significant researching into ceramic materials that can be made with greater thermal stability and desirable structural properties. Higher thermal stability allows for greater temperature difference between the lower and upper operating temperatures, hence greater thermodynamic efficiency.
The thermodynamic limits assume that the engine is operating under ideal conditions: a frictionless world, ideal gases, perfect insulators, and operation for infinite time. Real world applications introduce complexities that reduce efficiency. For example, a real engine runs best at a specific load, termed its power band. The engine in a car cruising on a highway is usually operating significantly below its ideal load, because it is designed for the higher loads required for rapid acceleration. In addition, factors such as wind resistance reduce overall system efficiency. Engine fuel economy is usually measured in the units of miles per gallon (or fuel consumption in liters per 100 kilometers) for automobiles. The volume of hydrocarbon assumes a standard energy content.
Most steel engines have a thermodynamic limit of 37%. Even when aided with turbochargers and stock efficiency aids, most engines retain an average efficiency of about 18%-20%. Rocket engine efficiencies are better still, up to 70%, because they operate at very high temperatures and pressures and can have very high expansion ratios.
There are many inventions aimed at increasing the efficiency of IC engines. In general, practical engines are always compromised by trade-offs between different properties such as efficiency, weight, power, heat, response, exhaust emissions, or noise. Sometimes economy also plays a role in not only the cost of manufacturing the engine itself, but also manufacturing and distributing the fuel. Increasing the engine's efficiency brings better fuel economy but only if the fuel cost per energy content is the same.
For stationary and shaft engines including propeller engines, fuel consumption is measured by calculating the brake specific fuel consumption, which measures the mass flow rate of fuel consumption divided by the power produced.
For internal combustion engines in the form of jet engines, the power output varies drastically with airspeed and a less variable measure is used: thrust specific fuel consumption (TSFC), which is the number of pounds of propellant needed to generate impulses that measure a pound force-hour. In metric units, the number of grams of propellant needed to generate an impulse that measures one kilonewton-second.
Internal combustion engines such as reciprocating internal combustion engines produce air pollution emissions, due to incomplete combustion of carbonaceous fuel. The main derivatives of the process are carbon dioxide CO2, water and some soot — also called particulate matter (PM). The effects of inhaling particulate matter have been studied in humans and animals and include asthma, lung cancer, cardiovascular issues, and premature death. There are, however, some additional products of the combustion process that include nitrogen oxides and sulfur and some uncombusted hydrocarbons, depending on the operating conditions and the fuel-air ratio.
Not all of the fuel is completely consumed by the combustion process; a small amount of fuel is present after combustion, and some of it reacts to form oxygenates, such as formaldehyde or acetaldehyde, or hydrocarbons not originally present in the input fuel mixture. Incomplete combustion usually results from insufficient oxygen to achieve the perfect stoichiometric ratio. The flame is "quenched" by the relatively cool cylinder walls, leaving behind unreacted fuel that is expelled with the exhaust. When running at lower speeds, quenching is commonly observed in diesel (compression ignition) engines that run on natural gas. Quenching reduces efficiency and increases knocking, sometimes causing the engine to stall. Incomplete combustion also leads to the production of carbon monoxide (CO). Further chemicals released are benzene and 1,3-butadiene that are also hazardous air pollutants.
Increasing the amount of air in the engine reduces emissions of incomplete combustion products, but also promotes reaction between oxygen and nitrogen in the air to produce nitrogen oxides (NOx). NOx is hazardous to both plant and animal health, and leads to the production of ozone (O3). Ozone is not emitted directly; rather, it is a secondary air pollutant, produced in the atmosphere by the reaction of NO"x" and volatile organic compounds in the presence of sunlight. Ground-level ozone is harmful to human health and the environment. Though the same chemical substance, ground-level ozone should not be confused with stratospheric ozone, or the ozone layer, which protects the earth from harmful ultraviolet rays.
In the United States, nitrogen oxides, PM, carbon monoxide, sulphur dioxide, and ozone, are regulated as criteria air pollutants under the Clean Air Act to levels where human health and welfare are protected. Other pollutants, such as benzene and 1,3-butadiene, are regulated as hazardous air pollutants whose emissions must be lowered as much as possible depending on technological and practical considerations.
Significant contributions to noise pollution are made by internal combustion engines. Automobile and truck traffic operating on highways and street systems produce noise, as do aircraft flights due to jet noise, particularly supersonic-capable aircraft. Rocket engines create the most intense noise.
Internal combustion engines continue to consume fuel and emit pollutants when idling so it is desirable to keep periods of idling to a minimum. Many bus companies now instruct drivers to switch off the engine when the bus is waiting at a terminus.
In the UK (but applying only to England), the Road Traffic Vehicle Emissions Fixed Penalty Regulations 2002 (Statutory Instrument 2002 No. 1808)  introduced the concept of a "stationary idling offence". This means that a driver can be ordered "by an authorised person ... upon production of evidence of his authorisation, require him to stop the running of the engine of that vehicle" and a "person who fails to comply ... shall be guilty of an offence and be liable on summary conviction to a fine not exceeding level 3 on the standard scale". Only a few local authorities have implemented the regulations, one of them being Oxford City Council.
Anyebe, E.A (2009). Combustion Engine and Operations, Automobile Technology Handbook, Vol. 2.
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