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LEAD - Somos Uno (Video Oficial)
LEAD - Somos Uno (Video Oficial)
Published: 2017/11/05
Channel: Lead
LEAD - La Cruz (Video Oficial)
LEAD - La Cruz (Video Oficial)
Published: 2017/03/03
Channel: Lead
LEAD - Espíritu Santo (Video Oficial)
LEAD - Espíritu Santo (Video Oficial)
Published: 2017/09/20
Channel: Lead
LEAD - Perfecto Amor (VideoClip Oficial)
LEAD - Perfecto Amor (VideoClip Oficial)
Published: 2017/06/23
Channel: Lead
LEAD feat  Un Corazón CD Amor Palabra Poder
LEAD feat Un Corazón CD Amor Palabra Poder
Published: 2017/01/04
Channel: Danny 11
【PV】トーキョーフィーバー / Lead
【PV】トーキョーフィーバー / Lead
Published: 2017/02/18
Channel: LeadOfficialCh
How Strong is a Solid Block of LEAD?
How Strong is a Solid Block of LEAD?
Published: 2017/05/31
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Lead: Last Week Tonight with John Oliver (HBO)
Lead: Last Week Tonight with John Oliver (HBO)
Published: 2016/04/18
Channel: LastWeekTonight
Mining Lead
Mining Lead
Published: 2016/07/15
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Andersen, Matthews lead Leafs past Habs, 6-0
Andersen, Matthews lead Leafs past Habs, 6-0
Published: 2017/11/19
Channel: NHL
Aho, Darling lead Canes past Sabres, 3-1
Aho, Darling lead Canes past Sabres, 3-1
Published: 2017/11/19
Channel: NHL
Thunder Blew 23 Point Lead vs Spurs! Wild Finish at Buzzer! 2017-18 Season
Thunder Blew 23 Point Lead vs Spurs! Wild Finish at Buzzer! 2017-18 Season
Published: 2017/11/18
Channel: Chris Smoove
James Harden (29/5/7) and Chris Paul (17/6) Lead Rockets Past Grizzlies | November 18, 2017
James Harden (29/5/7) and Chris Paul (17/6) Lead Rockets Past Grizzlies | November 18, 2017
Published: 2017/11/19
Channel: NBA
36 Questions That Lead to Love (Again)
36 Questions That Lead to Love (Again)
Published: 2017/11/18
Channel: The New York Times
Tatar, Larkin lead Red Wings to 3-1 win vs. Sabres
Tatar, Larkin lead Red Wings to 3-1 win vs. Sabres
Published: 2017/11/18
Channel: NHL
LEAD - Perfecto Amor - Lyric Video #AmorPalabraPoder
LEAD - Perfecto Amor - Lyric Video #AmorPalabraPoder
Published: 2016/07/12
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Lead - Periodic Table of Videos
Lead - Periodic Table of Videos
Published: 2008/09/16
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LEAD - Espíritu Santo (Lyric Video)
LEAD - Espíritu Santo (Lyric Video)
Published: 2017/09/21
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LEAD - Jesús
LEAD - Jesús
Published: 2016/11/02
Channel: Deep Music
Laine gets a piece of puck to give Jets lead over Devils
Laine gets a piece of puck to give Jets lead over Devils
Published: 2017/11/18
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LEAD - Agua en el desierto (En Vivo desde Casa de Dios #Hechos29)
LEAD - Agua en el desierto (En Vivo desde Casa de Dios #Hechos29)
Published: 2017/02/28
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76ers Blew 22 Point Lead vs Warriors! 47-15 3rd QTR! 2017-18 Season
76ers Blew 22 Point Lead vs Warriors! 47-15 3rd QTR! 2017-18 Season
Published: 2017/11/19
Channel: Chris Smoove
LEAD - Jesús - Lyric Video #AmorPalabraPoder
LEAD - Jesús - Lyric Video #AmorPalabraPoder
Published: 2016/12/11
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The battery lead the internet built
The battery lead the internet built
Published: 2017/11/19
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LEAD - Dámelo (Nuevo Single 2017)
LEAD - Dámelo (Nuevo Single 2017)
Published: 2017/04/20
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Roussel, Bishop lead Stars past Oilers, 6-3
Roussel, Bishop lead Stars past Oilers, 6-3
Published: 2017/11/19
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Kuznetsov, Holtby lead Capitals past Wild, 3-1
Kuznetsov, Holtby lead Capitals past Wild, 3-1
Published: 2017/11/19
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LEAD - Jesús (En Vivo desde Casa de Dios #Hechos29)
LEAD - Jesús (En Vivo desde Casa de Dios #Hechos29)
Published: 2017/03/16
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The Lead W/ Jake Tapper 11/17/17| Trump wants you not to believe his accusers
The Lead W/ Jake Tapper 11/17/17| Trump wants you not to believe his accusers
Published: 2017/11/17
Channel: Law Abiding Citizen
Warriors Blew 17 Pt Lead! Celtics 14 Game Win Streak! Warriors vs Celtics 2017-18 Season
Warriors Blew 17 Pt Lead! Celtics 14 Game Win Streak! Warriors vs Celtics 2017-18 Season
Published: 2017/11/17
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John Lennon
John Lennon's Lead Guitar Playing by Mike Pachelli
Published: 2017/11/16
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Molten Copper vs Lead Shot
Molten Copper vs Lead Shot
Published: 2016/03/21
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Lead Battery Recycling
Lead Battery Recycling
Published: 2009/02/20
Channel: HowStuffWorks
DVD/Blu-ray「Lead 15th Anniversary LIVE BOX」【TRAILER】
DVD/Blu-ray「Lead 15th Anniversary LIVE BOX」【TRAILER】
Published: 2017/11/02
Channel: LeadOfficialCh
RANGERS Lead The Way!  101st Airborne Rangers! (Guns Up! PC Gameplay)
RANGERS Lead The Way! 101st Airborne Rangers! (Guns Up! PC Gameplay)
Published: 2017/11/17
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LEAD - Dios de Milagros
LEAD - Dios de Milagros
Published: 2016/12/03
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【MV】Beautiful Day / Lead
【MV】Beautiful Day / Lead
Published: 2017/08/18
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Lead、15年の軌跡をノンストップで熱唱
Lead、15年の軌跡をノンストップで熱唱
Published: 2017/07/31
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LEAD - Jesús Ft. Julio Melgar (Videoclip Oficial)
LEAD - Jesús Ft. Julio Melgar (Videoclip Oficial)
Published: 2017/07/28
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Lead Me Lord - Gary Valenciano (w/ lyrics)
Lead Me Lord - Gary Valenciano (w/ lyrics)
Published: 2012/08/27
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Pistons Blew 22 Point Lead vs Pacers Last 18 Minutes! 2017-18 Season
Pistons Blew 22 Point Lead vs Pacers Last 18 Minutes! 2017-18 Season
Published: 2017/11/18
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Alexis Sanchez doubles Arsenal
Alexis Sanchez doubles Arsenal's lead over Spurs
Published: 2017/11/18
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Pouring Lead into the Keels
Pouring Lead into the Keels
Published: 2016/01/26
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Lead Me Lord by Gary Valenciano
Lead Me Lord by Gary Valenciano
Published: 2006/12/07
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Liên Quân Top 5 Ninja Lead đổ bộ tung hoành liên quân mùa 5 bạn đã biết ?
Liên Quân Top 5 Ninja Lead đổ bộ tung hoành liên quân mùa 5 bạn đã biết ?
Published: 2017/11/18
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Pogba adds to Man United
Pogba adds to Man United's lead over Newcastle
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LEAD - Dios de Milagros Ft. Christine D
LEAD - Dios de Milagros Ft. Christine D'Clario - Lyric Video
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LEAD - Acercarme (En vivo desde Casa de Dios)
LEAD - Acercarme (En vivo desde Casa de Dios)
Published: 2017/02/09
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Eden Hazard extends Chelsea
Eden Hazard extends Chelsea's lead over West Brom
Published: 2017/11/18
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LEAD - La Cruz Ft. Marcos Brunet
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WIKIPEDIA ARTICLE

From Wikipedia, the free encyclopedia
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Lead,  82Pb
A small gray metal cube surrounded by three gray metal nuggets in front of a light gray background
General properties
Pronunciation /ˈlɛd/ (LED)
Appearance metallic gray
Standard atomic weight (Ar, standard) 207.2(1)[1]
Lead in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Sn

Pb

Fl
thalliumleadbismuth
Atomic number (Z) 82
Group, period group 14 (carbon group), period 6
Block p-block
Element category   post-transition metal
Electron configuration [Xe] 4f14 5d10 6s2 6p2
Electrons per shell
2, 8, 18, 32, 18, 4
Physical properties
Phase (at STP) solid
Melting point 600.61 K ​(327.46 °C, ​621.43 °F)
Boiling point 2022 K ​(1749 °C, ​3180 °F)
Density (near r.t.) 11.34 g/cm3
when liquid (at m.p.) 10.66 g/cm3
Heat of fusion 4.77 kJ/mol
Heat of vaporization 179.5 kJ/mol
Molar heat capacity 26.650 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 978 1088 1229 1412 1660 2027
Atomic properties
Oxidation states 4, 3, 2, 1, −1, −2, −4 ​(an amphoteric oxide)
Electronegativity Pauling scale: 1.87 (+2)
Ionization energies
  • 1st: 715.6 kJ/mol
  • 2nd: 1450.5 kJ/mol
  • 3rd: 3081.5 kJ/mol
Atomic radius empirical: 175 pm
Covalent radius 146±5 pm
Van der Waals radius 202 pm
Color lines in a spectral range
Miscellanea
Crystal structure face-centered cubic (fcc)
Face-centered cubic crystal structure for lead
Speed of sound thin rod 1190 m/s (at r.t.) (annealed)
Thermal expansion 28.9 µm/(m·K) (at 25 °C)
Thermal conductivity 35.3 W/(m·K)
Electrical resistivity 208 nΩ·m (at 20 °C)
Magnetic ordering diamagnetic
Magnetic susceptibility −23.0×10−6 cm3/mol (at 298 K)[2]
Young's modulus 16 GPa
Shear modulus 5.6 GPa
Bulk modulus 46 GPa
Poisson ratio 0.44
Mohs hardness 1.5
Brinell hardness 38–50 MPa
CAS Number 7439-92-1
History
Discovery in the Middle East (7000 BCE)
Main isotopes of lead
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct
204Pb 1.4% stable
206Pb 24.1% stable
207Pb 22.1% stable
208Pb 52.4% stable
Isotopic abundances vary greatly by sample
| references | in Wikidata

Lead is a chemical element that is assigned the symbol Pb (from the Latin plumbum) and the atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and has a relatively low melting point. When freshly cut, lead is bluish-white; it tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and concludes three major decay chains of heavier elements.

Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited to organolead compounds. Like the lighter members of the group, lead tends to bond with itself; it can form chains, rings and polyhedral structures.

Lead is easily extracted from its ores; prehistoric people in Western Asia knew of it. Galena, a principal ore of lead, often bears silver, interest in which helped initiate widespread extraction and use of lead in ancient Rome. Lead production declined after the fall of Rome and did not reach comparable levels until the Industrial Revolution. In 2014, annual global production of lead was about ten million tonnes, over half of which was from recycling. Lead's high density, low melting point, ductility and relative inertness to oxidation make it useful. These properties, combined with its relative abundance and low cost, resulted in its extensive use in construction, plumbing, batteries, bullets and shot, weights, solders, pewters, fusible alloys, white paints, leaded gasoline, and radiation shielding.

In the late 19th century, lead's toxicity was recognized, and its use has since been phased out of many applications. Lead is a neurotoxin that accumulates in soft tissues and bones, damages the nervous system, and causes blood disorders. It is particularly problematic in children: even if blood levels are promptly normalized with treatment, permanent brain damage may result.

Physical properties[edit]

Atomic[edit]

A lead atom has 82 electrons, arranged in an electron configuration of [Xe]4f145d106s26p2. The combined first and second ionization energies—the total energy required to remove the two 6p electrons—is close to that of tin, lead's upper neighbor in the carbon group. This is unusual; ionization energies generally fall going down a group, as an element's outer electrons become more distant from the nucleus, and more shielded by smaller orbitals. The similarity of ionization energies is caused by the lanthanide contraction—the decrease in element radii from lanthanum (atomic number 57) to lutetium (71), and the relatively small radii of the elements after hafnium (72). This is due to poor shielding of the nucleus by the lanthanide 4f electrons. The combined first four ionization energies of lead exceed those of tin,[3] contrary to what periodic trends would predict. Relativistic effects, which become significant in heavier atoms, contribute to this behavior.[a] One such effect is the inert pair effect: the 6s electrons of lead become reluctant to participate in bonding, making the distance between nearest atoms in crystalline lead unusually long.[5]

Lead's lighter carbon group congeners form stable or metastable allotropes with the tetrahedrally coordinated and covalently bonded diamond cubic structure. The energy levels of their outer s- and p-orbitals are close enough to allow mixing into four hybrid sp3 orbitals. In lead, the inert pair effect increases the separation between its s- and p-orbitals, and the gap cannot be overcome by the energy that would be released by extra bonds following hybridization.[6] Rather than having a diamond cubic structure, lead forms metallic bonds in which only the p-electrons are delocalized and shared between the Pb2+ ions. Lead consequently has a face-centered cubic structure like the similarly sized divalent metals calcium and strontium.[7][b][c]

Bulk[edit]

Pure lead has a bright silvery appearance with a hint of blue.[11] It tarnishes on contact with moist air, and takes on a dull appearance the hue of which depends on the prevailing conditions. Characteristic properties of lead include high density, malleability, and high resistance to corrosion (due to passivation).[12]

A disk of metal
A sample of lead solidified from the molten state

Lead's close-packed face-centered cubic structure and high atomic weight result in a density[13] of 11.34 g/cm3, which is greater than that of common metals such as iron (7.87 g/cm3), copper (8.93 g/cm3), and zinc (7.14 g/cm3).[14] This density is the origin of the idiom to go over like a lead balloon.[15][16][d] Some rarer metals are denser: tungsten and gold are both 19.3 g/cm3, and osmium—the densest metal known—has a density of 22.59 g/cm3, almost twice that of lead.[17]

Lead is a very soft metal with a Mohs hardness of 1.5; it can be scratched with a fingernail.[18] It is quite malleable and somewhat ductile.[19][e] The bulk modulus of lead—a measure of its ease of compressibility—is 45.8 GPa. In comparison, that of aluminium is 75.2 GPa; copper 137.8 GPa; and mild steel 160–169 GPa.[20] Lead's tensile strength, at 12–17 MPa, is low (that of aluminium is 6 times higher, copper 10 times, and mild steel 15 times higher); it can be strengthened by adding small amounts of copper or antimony.[21]

The melting point of lead—at 327.5 °C (621.5 °F)[22]—is very low compared to most metals.[13][f] Its boiling point of 1749 °C (3180 °F)[22] is the lowest among the carbon group elements. The electrical resistivity of lead at 20 °C is 192 nanoohm-meters, almost an order of magnitude higher than those of other industrial metals (copper at 15.43 nΩ·m; gold 20.51 nΩ·m; and aluminium at 24.15 nΩ·m).[24] Lead is a superconductor at temperatures lower than 7.19 K;[25] this is the highest critical temperature of all type-I superconductors and the third highest of the elemental superconductors.[26]

Main isotopes of lead
Iso­tope Decay
abun­dance half-life (t1/2) mode pro­duct
202Pb syn 5.25(28)×104 y ε 202Tl
204Pb 1.4% stable
205Pb trace 1.53(7)×107 y ε 205Tl
206Pb 24.1% stable
207Pb 22.1% stable
208Pb 52.4% stable
209Pb trace 3.253(14) h β 209Bi
210Pb trace 22.3(22) y β 210Bi
211Pb trace 36.1(2) min β 211Bi
212Pb trace 10.64(1) h β 212Bi
214Pb trace 26.8(9) min β 214Bi
Isotopic abundances vary greatly by sample
Standard atomic weight (Ar, standard)

Isotopes[edit]

Natural lead consists of four stable isotopes with mass numbers of 204, 206, 207, and 208,[27] and traces of five short-lived radioisotopes.[28] The high number of isotopes is consistent with lead's atomic number being even.[g] Lead has a magic number of protons (82), for which the nuclear shell model accurately predicts an especially stable nucleus. Lead-208 has 126 neutrons, another magic number, which may explain why lead-208 is extraordinarily stable.[29]

With its high atomic number, lead is the heaviest element whose natural isotopes are regarded as stable; lead-208 is the heaviest stable nucleus. This title was formerly held by bismuth, with an atomic number of 83, until its only primordial isotope, bismuth-209, was found in 2003 to decay very slowly.[h] The four stable isotopes of lead could theoretically undergo alpha decay to isotopes of mercury with a release of energy, but this has not been observed for any of them; their predicted half-lives range from 1035 to 10189 years.[32]

Three of the stable isotopes are found in three of the four major decay chains: lead-206, lead-207, and lead-208 are the final decay products of uranium-238, uranium-235, and thorium-232, respectively. These decay chains are called the uranium series, the actinium series, and the thorium series. Their isotopic concentration in a natural rock sample depends greatly on the presence of these three parent uranium and thorium isotopes. For example, the relative abundance of lead-208 can range from 52% in normal samples to 90% in thorium ores;[33] for this reason, the standard atomic weight of lead is given to only one decimal place.[34] As time passes, the ratio of lead-206 and lead-207 to lead-204 increases, since the former two are supplemented by radioactive decay of heavier elements while the latter is not; this allows for lead–lead dating. As uranium decays into lead, their relative amounts change; this is the basis for uranium–lead dating.[35]

A piece of a gray meteorite on a pedestal
The Holsinger meteorite, the largest piece of the Canyon Diablo meteorite. Uranium–lead dating and lead–lead dating on this meteorite allowed refinement of the age of the Earth to 4.55 billion ± 70 million years.

Apart from the stable isotopes, which make up almost all lead that exists naturally, there are trace quantities of a few radioactive isotopes. One of them is lead-210; although it has a half-life of only 22.3 years,[27] small quantities occur in nature because lead-210 is produced by a long decay series that starts with uranium-238 (which has been present for billions of years on Earth). Lead-211, -212, and -214 are present in the decay chains of uranium-235, thorium-232, and uranium-238, respectively, so traces of all three of these lead isotopes are found naturally. Minute traces of lead-209 arise from the very rare cluster decay of radium-223, one of the daughter products of natural uranium-235. Lead-210 is particularly useful for helping to identify the ages of samples by measuring its ratio to lead-206 (both isotopes are present in a single decay chain).[36]

In total, 43 lead isotopes have been synthesized, with mass numbers 178–220.[27] Lead-205 is the most stable radioisotope, with a half-life of around 1.5×107 years.[i] The second-most stable is lead-202, which has a half-life of about 53,000 years, longer than any of the natural trace radioisotopes.[27]

Chemistry[edit]

A flame with a small metal rod penetrating it; the flame near the rod is pale blue.
Flame test: lead colors flame pale blue

Bulk lead exposed to moist air forms a protective layer of varying composition. Lead carbonate is a common constituent;[38][39][40] the sulfate or chloride may also be present in urban or maritime settings.[41] This layer makes bulk lead effectively chemically inert in the air.[41] Finely powdered lead, as with many metals, is pyrophoric,[42] and burns with a bluish-white flame.[43]

Fluorine reacts with lead at room temperature, forming lead(II) fluoride. The reaction with chlorine is similar but requires heating as the resulting chloride layer diminishes the reactivity of the elements.[41] Molten lead reacts with the chalcogens to give lead(II) chalcogenides.[44]

Lead metal resists sulfuric and phosphoric acid but not hydrochloric or nitric acid; the outcome depends on insolubility and subsequent passivation of the product salt.[45] Organic acids, such as acetic acid, dissolve lead in the presence of oxygen.[41] Concentrated alkalis will dissolve lead and form plumbites.[46]

Inorganic compounds[edit]

Lead shows two main oxidation states: +4 and +2. The tetravalent state is common for the carbon group. The divalent state is rare for carbon and silicon, minor for germanium, important (but not prevailing) for tin, and is the more important for lead.[41] This is attributable to relativistic effects, specifically the inert pair effect, which manifests itself when there is a large difference in electronegativity between lead and oxide, halide, or nitride anions, leading to a significant partial positive charge on lead. The result is a stronger contraction of the lead 6s orbital than is the case for the 6p orbital, making it rather inert in ionic compounds. This is less applicable to compounds in which lead forms covalent bonds with elements of similar electronegativity such as carbon in organolead compounds. In these, the 6s and 6p orbitals remain similarly sized and sp3 hybridization is still energetically favorable. Lead, like carbon, is predominantly tetravalent in such compounds.[47]

There is a relatively large difference in the electronegativity of lead(II) at 1.87 and lead(IV) at 2.33. This difference marks the reversal in the trend of increasing stability of the +4 oxidation state going down carbon group; tin, by comparison, has values of 1.80 in the +2 oxidation state and 1.96 in the +4 state.[48]

Lead(II)[edit]

Lead(II) compounds are characteristic of the inorganic chemistry of lead. Even strong oxidizing agents like fluorine and chlorine react with lead to give only PbF2 and PbCl2.[41] Lead(II) ions are usually colorless in solution,[49] and partially hydrolyze to form Pb(OH)+ and finally Pb4(OH)4 (in which the hydroxyl ions act as bridging ligands),[50][51] but are not reducing agents as tin(II) ions are. Techniques for identifying the presence of the Pb2+ ion in water generally rely on the precipitation of lead(II) chloride using dilute hydrochloric acid. As the chloride salt is somewhat soluble in water, the precipitation of lead(II) sulfide, by bubbling hydrogen sulfide through the solution, is then attempted.[52]

Lead monoxide exists in two polymorphs, red α-PbO and yellow β-PbO, the latter being stable only above around 488 °C. It is the most commonly used compound of lead.[53] Its lead(II) hydroxide counterpart can only exist in solution; it is known to form plumbite anions.[54] Lead commonly reacts with heavier chalcogens. Lead sulfide is a semiconductor, a photoconductor, and an extremely sensitive infrared radiation detector. The other two chalcogenides, lead selenide and lead telluride, are likewise photoconducting. They are unusual in that their color becomes lighter going down the group.[55]

Alternating dark gray and red balls connected by dark gray-red cylinders
     Lead and      oxygen in a tetragonal unit cell of lead(II,IV) oxide

Lead dihalides are well-characterized; this includes the diastatide,[56] and mixed halides, such as PbFCl. The relative insolubility of the latter forms a useful basis for the gravimetric determination of fluorine. The difluoride was the first solid ionically conducting compound to be discovered (in 1834, by Michael Faraday).[57] The other dihalides decompose on exposure to ultraviolet or visible light, especially the diiodide.[58] Many lead pseudohalides are known.[55] Lead(II) forms an extensive variety of halide coordination complexes, such as [PbCl4]2−, [PbCl6]4−, and the [Pb2Cl9]n5n chain anion.[58]

Lead(II) sulfate is insoluble in water, like the sulfates of other heavy divalent cations. Lead(II) nitrate and lead(II) acetate are very soluble, and this is exploited in the synthesis of other lead compounds.[59]

Lead(IV)[edit]

Few inorganic lead(IV) compounds are known, and these exist only in highly acidic solutions.[60] Lead(II) oxide gives a mixed oxide on further oxidation, Pb3O4. It is described as lead(II,IV) oxide, or structurally 2PbO·PbO2, and is the best-known mixed valence lead compound. Lead dioxide is a strong oxidizing agent, capable of oxidizing hydrochloric acid to chlorine gas. This is because the expected PbCl4 that would be produced is unstable and spontaneously decomposes to PbCl2 and Cl2. Analogously to lead monoxide, lead dioxide is capable of forming plumbate anions. Lead disulfide[61] and lead diselenide[62] are only stable at high pressures. Lead tetrafluoride, a yellow crystalline powder, is stable, but less so than the difluoride. Lead tetrachloride (a yellow oil) decomposes at room temperature, lead tetrabromide is less stable still, and the existence of lead tetraiodide is questionable.[63]

Nine dark gray spheres connected by cylinders of the same color forming a convex shape
The capped square antiprismatic anion [Pb9]4− from [K(18-crown-6)]2K2Pb9·(en)1.5[64]

Other oxidation states[edit]

Some lead compounds exist in formal oxidation states other than +4 or +2. Lead(III) may be obtained, as an intermediate between lead(II) and lead(IV), in larger organolead complexes; this oxidation state is not stable as both the lead(III) ion and the larger complexes containing it are radicals.[65][66][67] The same applies for lead(I), which can be found in such species.[68]

Numerous mixed lead(II,IV) oxides are known. When PbO2 is heated in air, it becomes Pb12O19 at 293 °C, Pb12O17 at 351 °C, Pb3O4 at 374 °C, and finally PbO at 605 °C. A further sesquioxide Pb2O3 can be obtained at high pressure, along with several non-stoichiometric phases. Many of them show defective fluorite structures in which some oxygen atoms are replaced by vacancies: PbO can be considered as having such a structure, with every alternate layer of oxygen atoms absent.[69]

Negative oxidation states can occur as Zintl phases, as either free lead anions, as in Ba2Pb, with lead formally being lead(−IV),[70] or in oxygen-sensitive ring-shaped or polyhedral cluster ions such as the trigonal bipyramidal Pb52− ion, where two lead atoms are lead(−I) and three are lead(0).[71] In such anions, each atom is at a polyhedral vertex and contributes two electrons to each covalent bond along an edge from their sp3 hybrid orbitals, the other two being an external lone pair.[50] They may be made in liquid ammonia via the reduction of lead by sodium.[72]

A gray-green sphere linked to four black spheres, each, in turn, linked also to three white ones
Structure of a tetraethyllead molecule:
     Carbon
     Hydrogen
     Lead

Organolead[edit]

Lead can form multiply bonded chains, a property it shares with its lighter homolog, carbon. Its capacity to do so is much less because the Pb–Pb bond energy is over three and a half times lower than that of the C–C bond.[44] With itself lead can build metal–metal bonds of an order up to three.[73] With carbon, lead forms organolead compounds similar to, but generally less stable than, typical organic compounds[74] (due to the Pb–C bond being rather weak).[50] This makes the organometallic chemistry of lead far less wide-ranging than that of tin.[75] It predominantly forms organolead(IV) compounds, even when starting with inorganic lead(II) reactants; very few organolead(II) compounds are known. The most well-characterized exceptions are Pb[CH(SiMe3)2]2 and Pb(η5-C5H5)2.[75]

The lead analog of the simplest organic compound, methane, is plumbane. Plumbane may be obtained in a reaction between metallic lead and atomic hydrogen.[76] Two simple derivatives, tetramethyllead and tetraethyllead, are the best-known organolead compounds. These compounds are relatively stable: tetraethyllead only starts to decompose if heated[77] or if exposed to sunlight or ultraviolet light.[78] (Tetraphenyllead is even more thermally stable, decomposing at 270 °C.[75]) With sodium metal, lead readily forms an equimolar alloy that reacts with alkyl halides to form organometallic compounds such as tetraethyllead.[79] The oxidizing nature of many organolead compounds is usefully exploited: lead tetraacetate is an important laboratory reagent for oxidation in organic chemistry[80] and tetraethyllead was once produced in larger quantities than any other organometallic compound.[75] Other organolead compounds are less chemically stable.[74] For many organic compounds, a lead analog does not exist.[76]

Origin and occurrence[edit]

Solar System abundances[81]
Atomic
number
Element Relative
amount
42 Molybdenum 0.798
46 Palladium 0.440
50 Tin 1.146
78 Platinum 0.417
80 Mercury 0.127
82 Lead 1
90 Thorium 0.011
92 Uranium 0.003

In space[edit]

Lead's per-particle abundance in the Solar System is 0.121 ppb (parts per billion).[81][j] This figure is two and a half times higher than that of platinum, eight times more than mercury, and seventeen times more than gold.[81] The amount of lead in the universe is slowly increasing[82] as most heavier atoms (all of which are unstable) gradually decay to lead.[83] The abundance of lead in the Solar System since its formation 4.5 billion years ago has increased by about 0.75%.[84] The solar system abundances table shows that lead, despite its relatively high atomic number, is more prevalent than most other elements with atomic numbers greater than 40.[81]

Primordial lead—which comprises the isotopes lead-204, lead-206, lead-207, and lead-208—was mostly created as a result of repetitive neutron capture processes occurring in stars. The two main modes of capture are the s- and r-processes.[85]

In the s-process (s is for "slow"), captures are separated by years or decades, allowing less stable nuclei to undergo beta decay. A stable thallium-203 nucleus can capture a neutron and become thallium-204; this undergoes beta decay to give stable lead-204; on capturing another neutron, it becomes lead-205, which has a half-life of around 15 million years. Further captures result in lead-206, lead-207, and lead-208. On capturing another neutron, lead-208 becomes lead-209, which quickly decays into bismuth-209. On capturing another neutron, bismuth-209 becomes bismuth-210, and this beta decays to polonium-210, which alpha decays to lead-206. The cycle hence ends at lead-206, lead-207, lead-208, and bismuth-209.[86]

Uppermost part of the nuclide chart, with only practically stable isotopes and lead-205 shown, and the path of the s-process overlaid on it as well that of the cycle on lead, bismuth, and polonium
Chart of the final part of the s-process, from mercury to polonium. Red lines and circles represent neutron captures; blue arrows represent beta decays; the green arrow represents an alpha decay; cyan arrows represent electron captures.

In the r-process (r is for "rapid"), captures happen faster than nuclei can decay. This occurs in environments with a high neutron density, such as a supernova or the merger of two neutron stars. The neutron flux involved may be on the order of 1022 neutrons per square centimeter per second.[87] The r-process does not form as much lead as the s-process. It tends to stop once neutron-rich nuclei reach 126 neutrons. At this point, the neutrons are arranged in complete shells in the atomic nucleus, and it becomes harder to energetically accommodate more of them. When the neutron flux subsides, these nuclei beta decay into stable isotopes of osmium, iridium, and platinum.[88]

On Earth[edit]

Lead is classified as a chalcophile under the Goldschmidt classification, meaning it is generally found combined with sulfur.[89] It rarely occurs in its native, metallic form.[90] Many lead minerals are relatively light and, over the course of the Earth's history, have remained in the crust instead of sinking deeper into the Earth's interior. This accounts for lead's relatively high crustal abundance of 14 ppm; it is the 38th most abundant element in the crust.[91][k]

The main lead-bearing mineral is galena (PbS), which is mostly found with zinc ores.[93] Most other lead minerals are related to galena in some way; boulangerite, Pb5Sb4S11, is a mixed sulfide derived from galena; anglesite, PbSO4, is a product of galena oxidation; and cerussite or white lead ore, PbCO3, is a decomposition product of galena. Arsenic, tin, antimony, silver, gold, copper, and bismuth are common impurities in lead minerals.[93]

A line chart generally declining towards its right
Lead is a fairly common element in the Earth's crust for its high atomic number (82). Most elements of atomic number greater than 40 are less abundant.

World lead resources exceed 2 billion tons. Significant deposits are located in Australia, China, Ireland, Mexico, Peru, Portugal, Russia, and the United States. Global reserves—resources that are economically feasible to extract—totaled 88 million tons in 2016, of which Australia had 35 million, China 17 million, and Russia 6.4 million.[94]

Typical background concentrations of lead do not exceed 0.1 μg/m3 in the atmosphere; 100 mg/kg in soil; and 5 μg/L in freshwater and seawater.[95]

Etymology[edit]

The modern English word "lead" is of Germanic origin; it comes from the Middle English leed and Old English lēad (with the macron above the "e" signifying that the vowel sound of that letter is long).[96] The Old English word is derived from the hypothetical reconstructed Proto-Germanic *lauda- ("lead").[97] According to linguistic theory, this word bore descendants in multiple Germanic languages of exactly the same meaning.[97]

The origin of the Proto-Germanic *lauda- is not agreed in the linguistic community. One hypothesis suggests it is derived from Proto-Indo-European *lAudh- ("lead"; capitalization of the vowel is equivalent to the macron).[98] Another hypothesis suggests it is borrowed from Proto-Celtic *ɸloud-io- ("lead"). This word is related to the Latin plumbum, which gave the element its chemical symbol Pb. The word *ɸloud-io- is thought to be the origin of Proto-Germanic *bliwa- (which also means "lead"), from which stemmed the German Blei.[99]

The name of the chemical element is not related to the verb of the same spelling, which is derived from Proto-Germanic *laidijan- ("to lead").[100]

History[edit]

A line chart generally growing to its right
World lead production peaking in the Roman period and the Industrial Revolution.[101]

Prehistory and early history[edit]

Metallic lead beads dating back to 7000–6500 BCE have been found in Asia Minor and may represent the first example of metal smelting.[102] At that time lead had few (if any) applications due to its softness and dull appearance.[102] The major reason for the spread of lead production was its association with silver, which may be obtained by burning galena (a common lead mineral).[103] The Ancient Egyptians were the first to use lead minerals in cosmetics, an application that spread to Ancient Greece and beyond;[104] the Egyptians may have used lead for sinkers in fishing nets, glazes, glasses, enamels, and for ornaments.[103] Various civilizations of the Fertile Crescent used lead as a writing material, as currency, and for construction.[103] Lead was used in the Ancient Chinese royal court as a stimulant,[103] as currency,[105] and as a contraceptive;[106] the Indus Valley civilization and the Mesoamericans[103] used it for making amulets; and the eastern and southern African peoples used lead in wire drawing.[107]

Classical era[edit]

Because silver was extensively used as a decorative material and an exchange medium, lead deposits came to be worked in Asia Minor since 3000 BCE; later, lead deposits were developed in the Aegean and Laurion. These three regions collectively dominated production of mined lead until c. 1200 BCE.[108] Since 2000 BCE, the Phoenicians worked deposits in the Iberian peninsula; by 1600 BCE, lead mining existed in Cyprus, Greece, and Sardinia.[109]

Ancient Greek lead sling bullets with a winged thunderbolt molded on one side and the inscription "ΔΕΞΑΙ" ("take that" or "catch") on the other side[110]

Rome's territorial expansion in Europe and across the Mediterranean, and its development of mining, led to it becoming the greatest producer of lead during the classical era, with an estimated annual output peaking at 80,000 tonnes. Like their predecessors, the Romans obtained lead mostly as a by-product of silver smelting.[101][111] Lead mining occurred in Central Europe, Britain, the Balkans, Greece, Anatolia, and Hispania, the latter accounting for 40% of world production.[101]

Lead was used for making water pipes in the Roman Empire; the Latin word for the metal, plumbum, is the origin of the English word "plumbing". Its ease of working and resistance to corrosion[112] ensured its widespread use in other applications including pharmaceuticals, roofing, currency, and warfare.[113][114][115] Writers of the time, such as Cato the Elder, Columella, and Pliny the Elder, recommended lead (or lead-coated) vessels for the preparation of sweeteners and preservatives added to wine and food. The lead conferred an agreeable taste due to the formation of "sugar of lead" (lead(II) acetate), whereas copper or bronze vessels could impart a bitter flavor through verdigris formation.[116]

This metal was by far the most used material in classical antiquity, and it is appropriate to refer to the (Roman) Lead Age. Lead was to the Romans what plastic is to us.
Heinz Eschnauer and Markus Stoeppler
"Wine—An enological specimen bank", 1992[117]

The Roman author Vitruvius reported the health dangers of lead[118] and modern writers have suggested that lead poisoning played a major role in the decline of the Roman Empire.[119][120][l] Other researchers have criticized such claims, pointing out, for instance, that not all abdominal pain is caused by lead poisoning.[122][123] According to archaeological research, Roman lead pipes increased lead levels in tap water but such an effect was "unlikely to have been truly harmful".[124][125] When lead poisoning did occur, victims were called "saturnine", dark and cynical, after the ghoulish father of the gods, Saturn. By association, lead was considered the father of all metals.[126] Its status in Roman society was low as it was readily available[127] and cheap.[128]

Ancient pipes in a museum case
Roman lead pipes[m]

Confusion with tin and antimony[edit]

During the classical era (and even up to the 17th century), tin was often not distinguished from lead: Romans called lead plumbum nigrum ("black lead"), and tin plumbum candidum ("bright lead"). The association of lead and tin can be seen in other languages: the word olovo in Czech translates to "lead", but in Russian the cognate олово (olovo) means "tin".[129] To add to the confusion, lead bore a close relation to antimony: both elements commonly occur as sulfides (galena and stibnite), often together. Pliny incorrectly wrote that stibnite would give lead on heating, instead of antimony.[130] In countries such as Turkey and India, the originally Persian name surma came to refer to either antimony sulfide or lead sulfide,[131] and in some languages, such as Russian, gave its name to antimony (сурьма).[132]

Middle Ages and the Renaissance[edit]

Lead mining in Western Europe declined after the fall of the Western Roman Empire, with Arabian Iberia being the only region having a significant output.[133][134] The largest production of lead occurred in South and East Asia, especially China and India, where lead mining grew strongly.[134]

A white-faced woman in red clothes
Elizabeth I of England was commonly depicted with a whitened face. Lead in face whiteners is thought to have contributed to her death.[135]

In Europe, lead production only began to revive in the 11th and 12th centuries, when it was again used for roofing and piping. Starting in the 13th century, lead was used to create stained glass.[136] In the European and Arabian traditions of alchemy, lead (symbol Saturn symbol.svg in the European tradition)[137] was considered an impure base metal which, by the separation, purification and balancing of its constituent essences, could be transformed to pure and incorruptible gold.[138] During the period, lead was used increasingly for adulterating wine. The use of such wine was forbidden for use in Christian rites by a papal bull in 1498, but it continued to be imbibed and resulted in mass poisonings up to the late 18th century.[133][139] Lead was a key material in parts of the printing press, which was invented around 1440; lead dust was commonly inhaled by print workers, causing lead poisoning.[140] Firearms were invented at around the same time, and lead, despite being more expensive than iron, became the chief material for making bullets. It was less damaging to iron gun barrels, had a higher density (which allowed for better retention of velocity), and its lower melting point made the production of bullets easier as they could be made using a wood fire.[141] Lead, in the form of Venetian ceruse, was extensively used in cosmetics by Western European aristocracy as whitened faces were regarded as a sign of modesty.[142][143] This practice later expanded to white wigs and eyeliners, and only faded out with the French Revolution in the late 18th century. A similar fashion appeared in Japan in the 18th century with the emergence of the geishas, a practice that continued long into the 20th century. The white faces of women "came to represent their feminine virtue as Japanese women",[144] with lead commonly used in the whitener.[145]

Outside Europe and Asia[edit]

In the New World, lead was produced soon after the arrival of European settlers. The earliest recorded lead production dates to 1621 in the English Colony of Virginia, fourteen years after its foundation.[146] In Australia, the first mine opened by colonists on the continent was a lead mine, in 1841.[147] In Africa, lead mining and smelting were known in the Benue Trough[148] and the lower Congo Basin, where lead was used for trade with Europeans, and as a currency by the 17th century,[149] well before the scramble for Africa.

A black-and-white drawing of men working in a mine
Lead mining in the upper Mississippi River region in the United States in 1865

Industrial Revolution[edit]

In the second half of the 18th century, Britain, and later continental Europe and the United States, experienced the Industrial Revolution. This was the first time during which production rates exceeded those of Rome.[101] Britain was the leading producer, losing this status by the mid-19th century with the depletion of its mines and the development of lead mining in Germany, Spain, and the United States.[150] By 1900, the United States was the leader in global lead production, and other non-European nations—Canada, Mexico, and Australia—had begun significant production; production outside Europe exceeded that within.[151] A great share of the demand for lead came from plumbing and painting—lead paints were in regular use.[152] At this time, more (working class) people were exposed to the metal and lead poisoning cases escalated. This led to research into the effects of lead intake. Lead was proven to be more dangerous in its fume form than as a solid metal. Lead poisoning and gout were linked; British physician Alfred Baring Garrod noted a third of his gout patients were plumbers and painters. The effects of chronic ingestion of lead, including mental disorders, were also studied in the 19th century. The first laws aimed at decreasing lead poisoning in factories were enacted during the 1870s and 1880s in the United Kingdom.[152]

A promotional poster for "COLLIER White Lead" (these words are highlighted) featuring a large image of a boy
Promotional poster for Dutch Boy lead paint, United States, 1912

Modern era[edit]

Further evidence of the threat that lead posed to humans was discovered in the late 19th and early 20th centuries. Mechanisms of harm were better understood, lead blindness was documented, and the element was phased out of public use in the United States and Europe. The United Kingdom introduced mandatory factory inspections in 1878 and appointed the first Medical Inspector of Factories in 1898; as a result, a 25-fold decrease in lead poisoning incidents from 1900 to 1944 was reported.[153] The last major human exposure to lead was the addition of tetraethyllead to gasoline as an antiknock agent, a practice that originated in the United States in 1921. It was phased out in the United States and the European Union by 2000.[152] Most European countries banned lead paint—commonly used because of its opacity and water resistance[154]—for interiors by 1930.[155]

In the 1970s, the United States and Western European countries introduced legislation to reduce lead air pollution.[156][157] The impact was significant: while a study conducted by the Centers for Disease Control and Prevention in the United States in 1976–1980 showed that 77.8% of population had elevated blood lead levels, in 1991–1994, a study by the same institute showed the share of people with such high levels dropped to 2.2%.[158] The main product made of lead by the end of the 20th century was the lead–acid battery,[159] which posed no direct threat to humans. From 1960 to 1990, lead output in the Western Bloc grew by a third.[160] The share of the world's lead production by the Eastern Bloc increased from 10% to 30%, from 1950 to 1990, with the Soviet Union being the world's largest producer during the mid-1970s and the 1980s, and China starting major lead production in the late 20th century.[161] Unlike the European communist countries, China was largely unindustrialized by the mid-20th century; in 2004, China surpassed Australia as the largest producer of lead.[162] As was the case during European industrialization, lead has had a negative effect on health in China.[163]

Production[edit]

A line chart of many lines, some longer than other, most generally growing towards its right
Primary production of lead since 1840

Production of lead is increasing worldwide due to its use in lead–acid batteries.[164] There are two major categories of production: primary from mined ores, and secondary from scrap. In 2014, 4.58 million metric tons came from primary production and 5.64 million from secondary production. The top three producers of mined lead concentrate in that year were China, Australia, and the United States. The top three producers of refined lead were China, the United States, and South Korea.[165] According to the International Resource Panel's Metal Stocks in Society report of 2010, the total amount of lead in use, stockpiled, discarded or dissipated into the environment, on a global basis, is 8 kg per capita. Much of this is in more developed countries (20–150 kg per capita) rather than less developed ones (1–4 kg per capita).[166]

Production processes for primary and secondary lead are similar. Some primary production plants now supplement their operations with scrap lead, and this trend is likely to increase in the future. Given adequate techniques, secondary lead is indistinguishable from primary lead. Scrap lead from the building trade is usually fairly clean and is re-melted without the need for smelting, though refining is sometimes needed. Secondary lead production is therefore cheaper, in terms of energy requirements, than is primary production, often by 50% or more.[167]

Primary[edit]

Most lead ores contain a low percentage of lead (rich ores have a typical content of 3–8%) which must be concentrated for extraction.[168] During initial processing, ores typically undergo crushing, dense-medium separation, grinding, froth flotation, and drying. The resulting concentrate, which has a lead content of 30–80% by mass (regularly 50–60%),[168] is then turned into (impure) lead metal.

There are two main ways of doing this: a two-stage process involving roasting followed by blast furnace extraction, carried out in separate vessels; or a direct process in which the extraction of the concentrate occurs in a single vessel. The latter has become the most common route, though the former is still significant.[169]

World's largest mining countries of lead, 2016[94]
Country Output
(thousand
tons)
 China 2,400
 Australia 500
 United States 335
 Peru 310
 Mexico 250
 Russia 225
 India 135
 Bolivia 80
 Sweden 76
 Turkey 75
 Iran 41
 Kazakhstan 41
 Poland 40
 South Africa 40
 North Korea 35
 Ireland 33
 Macedonia 33
Other countries 170

Two-stage process[edit]

First, the sulfide concentrate is roasted in air to oxidize the lead sulfide:[170]

2 PbS + 3 O2 → 2 PbO + 2 SO2

As the original concentrate was not pure lead sulfide, roasting yields lead oxide and a mixture of sulfates and silicates of lead and other metals contained in the ore.[171] This impure lead oxide is reduced in a coke-fired blast furnace to the (again, impure) metal:[172]

2 PbO + C → 2 Pb + CO2

Impurities are mostly arsenic, antimony, bismuth, zinc, copper, silver, and gold. The melt is treated in a reverberatory furnace with air, steam, and sulfur, which oxidizes the impurities except for silver, gold, and bismuth. Oxidized contaminants float to the top of the melt and are skimmed off.[173][174] Metallic silver and gold are removed and recovered economically by means of the Parkes process, in which zinc is added to lead. The zinc dissolves silver and gold, both of which, being immiscible in lead, can be separated and retrieved.[175][174] De-silvered lead is freed of bismuth by the Betterton–Kroll process, treating it with metallic calcium and magnesium. The resulting bismuth dross can be skimmed off.[174]

Very pure lead can be obtained by processing smelted lead electrolytically using the Betts process. Anodes of impure lead and cathodes of pure lead are placed in an electrolyte of lead fluorosilicate (PbSiF6). Once electrical potential is applied, impure lead at the anode dissolves and plates onto the cathode, leaving the majority of the impurities in solution.[174][176]

Direct process[edit]

In this process lead bullion and slag is obtained directly from lead concentrates. The lead sulfide concentrate is melted in a furnace and oxidized, forming lead monoxide. Carbon (coke or coal gas[n]) is added to the molten charge along with fluxing agents. The lead monoxide is thereby reduced to metallic lead, in the midst of a slag rich in lead monoxide.[169]

As much as 80% of the lead in very high-content initial concentrates can be obtained as bullion; the remaining 20% forms a slag rich in lead monoxide. For a low-grade feed, all of the lead can be oxidized to a high-lead slag.[169] Metallic lead is further obtained from the high-lead (25–40%) slags via submerged fuel combustion or injection, reduction assisted by an electric furnace, or a combination of both.[169]

Alternatives[edit]

Research on a cleaner, less energy-intensive lead extraction process continues; a major drawback is that either too much lead is lost as waste, or the alternatives result in a high sulfur content in the resulting lead metal. Hydrometallurgical extraction, in which anodes of impure lead are immersed into an electrolyte and pure lead is deposited onto a cathode, is a technique that may have potential.[177]

Secondary[edit]

Smelting, which is an essential part of the primary production, is often skipped during secondary production. It is only performed when metallic lead had undergone significant oxidation.[167] The process is similar to that of primary production in either a blast furnace or a rotary furnace, with the essential difference being the greater variability of yields. The Isasmelt process is a more recent method that may act as an extension to primary production; battery paste from spent lead–acid batteries has sulfur removed by treating it with alkali, and is then treated in a coal-fueled furnace in the presence of oxygen, which yields impure lead, with antimony the most common impurity.[178] Refining of secondary lead is similar to that of primary lead; some refining processes may be skipped depending on the material recycled and its potential contamination, with bismuth and silver most commonly being accepted as impurities.[178]

Of the sources of lead for recycling, lead–acid batteries are the most important; lead pipe, sheet, and cable sheathing are also significant.[167]

Applications[edit]

A closed structure of black bricks
Bricks of lead (alloyed with 4% antimony) are used as radiation shielding.[179]

Contrary to popular belief, pencil leads in wooden pencils have never been made from lead. When the pencil originated as a wrapped graphite writing tool, the particular type of graphite used was named plumbago (literally, act for lead or lead mockup).[180]

Elemental form[edit]

Lead metal has several useful mechanical properties, including high density, low melting point, ductility, and relative inertness. Many metals are superior to lead in some of these aspects but are generally less common and more difficult to extract from parent ores. Lead's toxicity has led to its phasing out for some uses.[181]

Lead has been used for bullets since their invention in the Middle Ages. It is inexpensive; its low melting point means small arms ammunition and shotgun pellets can be cast with minimal technical equipment; and it is denser than other common metals, which allows for better retention of velocity. Concerns have been raised that lead bullets used for hunting can damage the environment.[o]

Its high density and resistance to corrosion have been exploited in a number of related applications. It is used as ballast in sailboat keels.[183] Its weight allows it to counterbalance the heeling effect of wind on the sails; being so dense it takes up a small volume and minimizes water resistance. It is used in scuba diving weight belts to counteract the diver's buoyancy.[184] In 1993, the base of the Leaning Tower of Pisa was stabilized with 600 tonnes of lead.[185] Because of its corrosion resistance, lead is used as a protective sheath for underwater cables.[186]

A yellow sculpture in a park
A 17th-century gold-coated lead sculpture

Lead has many uses in the construction industry; lead sheets are used as architectural metals in roofing material, cladding, flashing, gutters and gutter joints, and on roof parapets.[187][188] Detailed lead moldings are used as decorative motifs to fix lead sheet. Lead is still used in statues and sculptures,[p] including for armatures.[190] In the past it was often used to balance the wheels of cars; for environmental reasons this use is being phased out in favor of other materials.[94]

Lead is added to copper alloys such as brass and bronze, to improve machinability and for its lubricating qualities. Being practically insoluble in copper the lead forms solid globules in imperfections throughout the alloy, such as grain boundaries. In low concentrations, as well as acting as a lubricant, the globules hinder the formation of swarf as the alloy is worked, thereby improving machinability. Copper alloys with larger concentrations of lead are used in bearings. The lead provides lubrication, and the copper provides the load-bearing support.[191]

Lead's high density, atomic number, and formability form the basis for use of lead as a barrier that absorbs sound, vibration, and radiation.[192] Lead has no natural resonance frequencies;[192] as a result, sheet-lead is used as a sound deadening layer in the walls, floors, and ceilings of sound studios.[193] Organ pipes are often made from a lead alloy, mixed with various amounts of tin to control the tone of each pipe.[194][195] Lead is an established shielding material from radiation in nuclear science and in X-ray rooms[196] due to its denseness and high attenuation coefficient.[197] Molten lead has been used as a coolant for lead-cooled fast reactors.[198]

A glass flagon before a black background
A lead glass flagon

The largest use of lead in the early 21st century is in lead–acid batteries. The reactions in the battery between lead, lead dioxide, and sulfuric acid provide a reliable source of voltage.[q] The lead in batteries undergoes no direct contact with humans, so there are fewer toxicity concerns. Supercapacitors incorporating lead–acid batteries have been installed in kilowatt and megawatt scale applications in Australia, Japan, and the United States in frequency regulation, solar smoothing and shifting, wind smoothing, and other applications.[200] These batteries have lower energy density and charge-discharge efficiency than lithium-ion batteries, but are significantly cheaper.[201]

Lead is used in high voltage power cables as sheathing material to prevent water diffusion into insulation; this use is decreasing as lead is being phased out.[202] Its use in solder for electronics is also being phased out by some countries to reduce the amount of environmentally hazardous waste.[203] Lead is one of three metals used in the Oddy test for museum materials, helping detect organic acids, aldehydes, and acidic gases.[204][205]

Compounds[edit]

Lead compounds are used as, or in, coloring agents, oxidants, plastic, candles, glass, and semiconductors. Lead-based coloring agents are used in ceramic glazes and glass, especially for red and yellow shades.[206] Lead tetraacetate and lead dioxide are used as oxidizing agents in organic chemistry. Lead is frequently used in the polyvinyl chloride coating of electrical cords.[207][208] It can be used to treat candle wicks to ensure a longer, more even burn. Because of its toxicity, European and North American manufacturers use alternatives such as zinc.[209][210] Lead glass is composed of 12–28% lead oxide, changing its optical characteristics and reducing the transmission of ionizing radiation.[211] Lead-based semiconductors such as lead telluride and lead selenide are used in photovoltaic cells and infrared detectors.[212]

Biological effects[edit]

A chart of a human body with arrows pointing pieces of text to different parts of the body
Symptoms of lead poisoning

Biological[edit]

Lead has no confirmed biological role.[213] Its prevalence in the human body—at an adult average of 120 mg[r]—is nevertheless exceeded only by zinc (2500 mg) and iron (4000 mg) among the heavy metals.[215] Lead salts are very efficiently absorbed by the body.[216] A small amount of lead (1%) is stored in bones; the rest is excreted in urine and feces within a few weeks of exposure. Only about a third of lead is excreted by a child. Continual exposure may result in the bioaccumulation of lead.[217]

Toxicity[edit]

Lead is a highly poisonous metal (whether inhaled or swallowed), affecting almost every organ and system in the human body.[218] At airborne levels of 100 mg/m3, it is immediately dangerous to life and health.[219] Most ingested lead is absorbed into the bloodstream.[220] The primary cause of its toxicity is its predilection for interfering with the proper functioning of enzymes. It does so by binding to the sulfhydryl groups found on many enzymes,[221] or mimicking and displacing other metals which act as cofactors in many enzymatic reactions.[222] Among the essential metals that lead interacts with are calcium, iron, and zinc.[223] High levels of calcium and iron tend to provide some protection from lead poisoning; low levels cause increased susceptibility.[216]

Effects[edit]

Lead can cause severe damage to the brain and kidneys and, ultimately, death. By mimicking calcium, lead can cross the blood-brain barrier. It degrades the myelin sheaths of neurons, reduces their numbers, interferes with neurotransmission routes, and decreases neuronal growth.[221]

Symptoms of lead poisoning include nephropathy, colic-like abdominal pains, and possibly weakness in the fingers, wrists, or ankles. Small blood pressure increases, particularly in middle-aged and older people, may be apparent and can cause anemia. Several studies, mostly cross-sectional, found an association between increased lead exposure and decreased heart rate variability.[224] In pregnant women, high levels of exposure to lead may cause miscarriage. Chronic, high-level exposure has been shown to reduce fertility in males.[225]

Kymographic recording of the effect of lead acetate on frog heart experimental set up.

In a child's developing brain, lead interferes with synapse formation in the cerebral cortex, neurochemical development (including that of neurotransmitters), and the organization of ion channels.[226] Early childhood exposure has been linked with an increased risk of sleep disturbances and excessive daytime sleepiness in later childhood.[227] High blood levels are associated with delayed puberty in girls.[228] The rise and fall in exposure to airborne lead from the combustion of tetraethyl lead in gasoline during the 20th century has been linked with historical increases and decreases in crime levels, a hypothesis which is not universally accepted.[229]

Exposure sources[edit]

Lead exposure is a global issue since lead mining and smelting, and battery manufacturing/disposal/recycling, are common in many countries. Lead enters the body via inhalation, ingestion, or skin absorption. Almost all inhaled lead is absorbed into the body; for ingestion, the rate is 20–70%, with children absorbing a higher percentage than adults.[230]

Poisoning typically results from ingestion of food or water contaminated with lead, and less commonly after accidental ingestion of contaminated soil, dust, or lead-based paint.[231] Seawater products can contain lead if affected by nearby industrial waters.[232] Fruit and vegetables can be contaminated by high levels of lead in the soils they were grown in. Soil can be contaminated through particulate accumulation from lead in pipes, lead paint, and residual emissions from leaded gasoline.[233]

The use of lead for water pipes is problematic in areas with soft or acidic water.[234] Hard water forms insoluble layers in the pipes whereas soft and acidic water dissolves the lead pipes.[235] Dissolved carbon dioxide in the carried water may result in the formation of soluble lead bicarbonate; oxygenated water may similarly dissolve lead as lead(II) hydroxide.[236] Drinking such water, over time, can cause health problems due to the toxicity of the dissolved lead. The harder the water the more calcium bicarbonate and sulfate it will contain, and the more the inside of the pipes will be coated with a protective layer of lead carbonate or lead sulfate.[237]

Ingestion of applied lead-based paint is the major source of exposure for children: a direct source is chewing on old painted window sills. Alternatively, as the applied dry paint deteriorates, it peels, is pulverized into dust and then enters the body through hand-to-mouth contact or contaminated food, water, or alcohol. Ingesting certain home remedies may result in exposure to lead or its compounds.[238]

NFPA 704
fire diamond
Flammability code 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g., canola oil Health code 3: Short exposure could cause serious temporary or residual injury. E.g., chlorine gas Reactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g., liquid nitrogen Special hazards (white): no codeNFPA 704 four-colored diamond
Fire diamond for lead granules

Inhalation is the second major exposure pathway, affecting smokers and especially workers in lead-related occupations.[220] Cigarette smoke contains, among other toxic substances, radioactive lead-210.[239]

Skin exposure may be significant for people working with organic lead compounds. The rate of skin absorption is lower for inorganic lead.[240]

Treatment[edit]

Treatment for lead poisoning normally involves the administration of dimercaprol and succimer.[241] Acute cases may require the use of disodium calcium edetate, the calcium chelate of the disodium salt of ethylenediaminetetraacetic acid (EDTA). It has a greater affinity for lead than calcium, with the result that lead chelate is formed by exchange and excreted in the urine, leaving behind harmless calcium.[242]

Environmental effects[edit]

A dusty dump
Battery collection site in Dakar, Senegal, where at least 18 children died of lead poisoning in 2008

The extraction, production, use, and disposal of lead and its products have caused significant contamination of the Earth's soils and waters. Atmospheric emissions of lead were at their peak during the Industrial Revolution, and the leaded gasoline period in the second half of the twentieth century. Elevated concentrations of lead persist in soils and sediments in post-industrial and urban areas; industrial emissions, including those arising from coal burning,[243] continue in many parts of the world, particularly in the developing countries.[244]

Lead can accumulate in soils, especially those with a high organic content, where it remains for hundreds to thousands of years. It can take the place of other metals in plants and can accumulate on their surfaces, thereby retarding photosynthesis, and preventing their growth or killing them. Contamination of soils and plants then affects microorganisms and animals. Affected animals have a reduced ability to synthesize red blood cells, which causes anemia.[245]

Analytical methods for the determination of lead in the environment include spectrophotometry, X-ray fluorescence, atomic spectroscopy and electrochemical methods. A specific ion-selective electrode has been developed based on the ionophore S,S'-methylenebis(N,N-diisobutyldithiocarbamate).[246]

Restriction and remediation[edit]

An X-ray picture with numerous small pellets highlighted in white
Radiography of a swan found dead in Condé-sur-l'Escaut (northern France), highlighting lead shot. There are hundreds of lead pellets; a dozen is enough to kill an adult swan within a few days. Such bodies are sources of environmental contamination by lead.

By the mid-1980s, a significant shift in lead use had taken place. In the United States, environmental regulations reduced or eliminated the use of lead in non-battery products, including gasoline, paints, solders, and water systems. Particulate control devices can be used in coal-fired power plants to capture lead emissions.[243] Lead use is being further curtailed by the European Union's Restriction of Hazardous Substances Directive.[247] The use of lead shot for hunting and sport shooting was banned by the Netherlands in 1993, resulting in a large drop in lead emissions from 230 tonnes in 1990 to 47.5 tonnes in 1995.[248]

In the United States, the permissible exposure limit for lead in the workplace, comprising metallic lead, inorganic lead compounds, and lead soaps, is 0.05 mg/m3 over an 8-hour workday, and the recommended blood lead level limit is 0.04 mg per 100 g of blood.[220] Lead may still be found in harmful quantities in stoneware,[249] vinyl[250] (such as that used for tubing and the insulation of electrical cords), and Chinese brass.[s] Old houses may still contain lead paint.[250] White lead paint has been withdrawn from sale in industrialized countries, but specialized uses of other pigments such as yellow lead chromate remain.[154] Stripping old paint by sanding produces dust which can be inhaled.[252] Lead abatement programs have been mandated by some authorities in properties where young children live.[253]

Lead waste, depending of the jurisdiction and the nature of the waste, may be treated as household waste (in order to facilitate lead abatement activities),[254] or potentially hazardous waste requiring specialized treatment or storage.[255] Research has been conducted on how to remove lead from biosystems by biological means. Fish bones are being researched for their ability to bioremediate lead in contaminated soil.[256][257] The fungus Aspergillus versicolor is effective at removing lead ions.[258] Several bacteria have been researched for their ability to remove lead from the environment, including the sulfate-reducing bacteria Desulfovibrio and Desulfotomaculum, both of which are highly effective in aqueous solutions.[259]

Notes[edit]

  1. ^ About 10% of the lanthanide contraction has been attributed to relativistic effects.[4]
  2. ^ The tetrahedral allotrope of tin is called α- or gray tin and is stable only at or below 13.2 °C (55.8 °F). The stable form of tin above this temperature is called β- or white tin and has a distorted face centered cubic (tetragonal) structure which can be derived by compressing the tetrahedra of gray tin along their cubic axes. White tin effectively has a structure intermediate between the regular tetrahedral structure of gray tin, and the regular face centered cubic structure of lead, consistent with the general trend of increasing metallic character going down any representative group.[8]
  3. ^ A quasicrystalline thin-film allotrope of lead, with pentagonal symmetry, was reported in 2013. The allotrope was obtained by depositing lead atoms on the surface of an icosahedral silver-indium-ytterbium quasicrystal. Its conductivity was not recorded.[9][10]
  4. ^ British English: to go down like a lead balloon.
  5. ^ Malleability describes how easily it deforms under compression, whereas ductility means its ability to stretch.
  6. ^ A (wet) finger can be dipped into molten lead without risk of a burning injury.[23]
  7. ^ An even number of either protons or neutrons generally increases the nuclear stability of isotopes, compared to isotopes with odd numbers. No elements with odd atomic numbers have more than two stable isotopes; even-numbered elements have multiple stable isotopes, with tin (element 50) having the highest number of isotopes of all elements, ten.[27] See Even and odd atomic nuclei for more details.
  8. ^ The half-life found in the experiment was 1.9×1019 years.[30] A kilogram of natural bismuth would have an activity value of approximately 0.003 becquerels (decays per second). For comparison, the activity value of natural radiation in the human body is around 65 becquerels per kilogram of body weight (4500 becquerels on average).[31]
  9. ^ Lead-205 decays solely via electron capture, which means when there are no electrons available and lead is fully ionized with all 82 electrons removed it cannot decay. Fully ionized thallium-205, the isotope lead-205 would decay to, becomes unstable and can decay into a bound state of lead-205.[37]
  10. ^ Abundances in the source are listed relative to silicon rather than in per-particle notation. The sum of all elements per 106 parts of silicon is 2.6682×1010 parts; lead comprises 3.258 parts.
  11. ^ Elemental abundance figures are estimates and their details may vary from source to source.[92]
  12. ^ The fact that Julius Caesar fathered only one child, as well as the alleged sterility of his successor, Caesar Augustus, have been attributed to lead poisoning.[121]
  13. ^ The inscription reads: "Made when the Emperor Vespasian was consul for the ninth term and the Emperor Titus was consul for the seventh term, when Gnaeus Iulius Agricola was imperial governor (of Britain)."
  14. ^ Gaseous by-product of the coking process, containing carbon monoxide, hydrogen and methane; used as a fuel.
  15. ^ California began banning lead bullets for hunting on that basis in July 2015.[182]
  16. ^ For example, a firm "...producing quality [lead] garden ornament from our studio in West London for over a century".[189]
  17. ^ See[199] for details on how a lead–acid battery works.
  18. ^ Rates vary greatly by country.[214]
  19. ^ An alloy of brass (copper and zinc) with lead, iron, tin, and sometimes antimony.[251]

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Bibliography[edit]

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External links[edit]

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